{"id":152,"date":"2025-07-04T23:46:24","date_gmt":"2025-07-04T23:46:24","guid":{"rendered":"https:\/\/jayaramangroup.faculty.unlv.edu\/?page_id=152"},"modified":"2026-03-24T22:03:18","modified_gmt":"2026-03-24T22:03:18","slug":"publications","status":"publish","type":"page","link":"https:\/\/jayaramangroup.faculty.unlv.edu\/?page_id=152","title":{"rendered":"Publications"},"content":{"rendered":"\n

PUBLICATIONS<\/p>\n\n\n\n

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GoogleScholar<\/a><\/p>\n<\/div>\n\n\n\n

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ORCiD<\/a><\/p>\n<\/div>\n\n\n\n

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ResearchGate<\/a><\/p>\n<\/div>\n<\/div>\n\n\n\n

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30) Olefin \u03c0-coordination chemistry at low-oxidation-state boron<\/a><\/p>\n\n\n\n

Maximilian Michel, Marco Weber, Arumugam Jayaraman, Rian D. Dewhurst, Ivo Krummenacher, Christian Voigt, Marcel H\u00e4rterich, Alfredo Vargas, and Holger Braunschweig\u2009\u2009<\/p>\n\n\n\n

Nature Chem.,<\/em> 2026<\/strong>, 18<\/em>, 135\u2212141<\/p>\n\n\n\n

Highlighted in:<\/em><\/p>\n\n\n\n

Uni-Wuerzburg<\/a><\/td>EurekAlert<\/a><\/td>Mirage News<\/a> <\/td>Chem Europe<\/a><\/td>ScienMag<\/a><\/td><\/tr>
My Science<\/a><\/td>Ingenieur.de<\/a> <\/td><\/a>LaRep\u00fablica.es<\/a><\/td>Bioengineer.org<\/a> <\/td>phys.org<\/a> <\/td><\/tr>
Jura Forum<\/a><\/td>Analytik NEWS<\/a><\/td>MSN<\/a><\/td>AlphaGalileo<\/a> <\/td> idw<\/a> <\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n
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29) Formation and metallomimetic reactivity of a transient dicoordinate alkylborylene<\/a><\/p>\n\n\n\n

Yannick Konrad, Arumugam Jayaraman, Ivo Krummenacher, and Holger Braunschweig<\/p>\n\n\n\n

Angew. Chem. Int. Ed.,<\/em> 2025<\/strong>, 64<\/em>, e202423669<\/p>\n\n\n\n

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28) Straightforward formation of borirenes from boroles and dialkynes<\/a><\/p>\n\n\n\n

Pedro H. R. Oliveira, Marieli O. Rodrigues, Caren D. G. Da Silva, Josina L. Bohlen, Merle Arrowsmith, <\/strong>Arumugam Jayaraman, Lukas Lubczyk, Felipe Fantuzzi, Eufr\u00e2nio N. da Silva J\u00fanior, and Holger Braunschweig<\/p>\n\n\n\n

Angew. Chem. Int. Ed.,<\/em> 2025<\/strong>, 64<\/em>, e202423391<\/p>\n\n\n\n

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27) Reactivity of a stable and highly electron-rich (\u03b76 \u2011Diborabenzene)nickel(0) synthon<\/a><\/p>\n\n\n\n

Maximilian Dietz, Merle Arrowsmith, Arumugam Jayaraman, Anna Lamprecht, and Holger Braunschweig<\/p>\n\n\n\n

Inorg. Chem<\/em>. 2025<\/strong>, 64<\/em>, 1788\u22121797<\/p>\n\n\n\n

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26) Intermolecular 1,2-aminoboration of alkynes and the critical role of electron-rich alkynes<\/a><\/p>\n\n\n\n

Simon Dotzauer, Arumugam Jayaraman, David Reinhart, Holger Braunschweig<\/p>\n\n\n\n

Angew. Chem. Int. Ed.,<\/em> 2024<\/strong>, 63<\/em>, e202413370<\/p>\n\n\n\n

Highlighted as a Hot Paper<\/strong><\/em><\/p>\n\n\n\n

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25) Experimental observation of a terminal borylene-dinitrogen adduct via cleavage of a 1,2,3,4,5 diboratriazoline<\/a><\/p>\n\n\n\n

Arumugam Jayaraman, Benedikt Ritschel, Merle Arrowsmith, Christian Markl, Malte J\u00fcrgensen, Anel Halki\u0107, Yannick Konrad, Andreas Stoy, Krzysztof Radacki, Holger Braunschweig<\/p>\n\n\n\n

Angew. Chem. Int. Ed., <\/em>2024<\/strong>, 63<\/em>, 202412307<\/p>\n\n\n\n

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24) Full electron delocalization across the cluster in 1,12-bis<\/em>BMes2-p<\/em>-carborane radical anion<\/a><\/p>\n\n\n\n

Lin Wu, Xinning Zhang, Michael Moos, Ivo Krummenacher, Maximillian Dietz, Arumugam Jayaraman, R\u00fcdiger Bertermann, Qing Ye, Maik Finze, Christoph Lambert, Holger Braunschweig, and Lei Ji<\/p>\n\n\n\n

J. Am. Chem. Soc.<\/em>, 2024<\/strong>, 146, 17956\u201317963<\/p>\n\n\n\n

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23) Trapping of a transient base-stabilised alumylene and alumylene-type reactivity of a self-stabilising dialumene towards organic azides<\/a><\/p>\n\n\n\n

Debabrata Dhara, Arumugam Jayaraman, Marcel H\u00e4rterich, Merle Arrowsmith, Malte J\u00fcrgensen, Maximilian Michel and Holger Braunschweig<\/p>\n\n\n\n

Chem. Eur. J.<\/em>, 2023<\/strong>, 29<\/em>, e202300483<\/strong><\/p>\n\n\n\n

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22) Carbodicarbenes and striking redox transitions of their conjugate acids: Influence of NHC versus CAAC as donor substituents<\/a><\/p>\n\n\n\n

Ramapada Dolai, Rahul Kumar, Benedict J Elvers, Pradeep Kumar Pal, Benson Joseph, Rina Sikari, Mithilesh Kumar Nayak, Avijit Maiti, Tejender Singh, Nicolas Chrysochos, Arumugam Jayaraman, Ivo Krummenacher, Jagannath Mondal, U. Deva Priyakumar, Holger Braunschweig, Cem B. Yildiz, Carola Schulzke and Anukul Jana<\/p>\n\n\n\n

Chem. Eur. J.<\/em>, 2022<\/strong>, 29<\/em>, e202202888<\/p>\n\n\n\n

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21) Synthesis and hydrogenation of polycyclic aromatic hydrocarbon-substituted diborenes via uncatalyzed hydrogenative B\u2012C bond cleavage<\/a><\/p>\n\n\n\n

Alexander Okorn, Arumugam Jayaraman, Lukas Englert, Merle Arrowsmith, Theresa Swoboda, Jeanette Weigelt, Carina Brunecker, Merlin Hess, Anna Lamprecht, Carsten Lenczyk, Maximilian Rang and Holger Braunschweig<\/p>\n\n\n\n

Chem. Sci.<\/em>, 2022<\/strong>, 13<\/em>, 7566\u22127574<\/p>\n\n\n\n

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20) Generation of a transient base-stabilised arylalumylene for the facile deconstruction of aromatic molecules<\/a><\/p>\n\n\n\n

Debabrata Dhara, Arumugam Jayaraman, Marcel H\u00e4rterich, Rian D. Dewhurst and Holger Braunschweig<\/p>\n\n\n\n

Chem. Sci.<\/em>, 2022<\/strong>, 13<\/em>, 5631\u20135638<\/p>\n\n\n\n

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19) Diboramacrocycles: reversible borole dimerisation-dissociation systems<\/a><\/p>\n\n\n\n

Sonja Fuchs, Arumugam Jayaraman, Ivo Krummenacher, Laura Haley, Marta Ba\u0161tovanovi\u0107, Maximilian Fest, Krzysztof Radacki, Holger Helten and Holger Braunschweig<\/p>\n\n\n\n

Chem. Sci.<\/em>, 2022<\/strong>, 13<\/em>, 2932\u20132938<\/p>\n\n\n\n

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18) Azide-alkyne cycloadditions with an electronically activated alkyne: indole formation via <\/em>1-aryl-1,2,3-triazole-derived imino carbenes<\/a><\/p>\n\n\n\n

Stephanie Kachel, Arumugam Jayaraman, Alexander Okorn, Ivo Krummenacher, Regina Drescher, Carina Brunecker, Sonja Fuchs, Merlin He\u00df, Tom E. Stennett and Holger Braunschweig<\/p>\n\n\n\n

Chem. Commun.<\/em>, 2022<\/strong>, 58<\/em>, 2331\u20132334<\/p>\n\n\n\n

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17) An unsymmetrical, cyclic diborene based on a chelating CAAC ligand and its small-molecule activation and rearrangement chemistry<\/a><\/p>\n\n\n\n

Wei Lu, Arumugam Jayaraman, Felipe Fantuzzi, Rian D. Dewhurst, Marcel H\u00e4rterich, Maximilian Dietz, Stephan Hagspiel, Ivo Krummenacher, Kai Hammond, Jingjing Cui and Holger Braunschweig<\/p>\n\n\n\n

Angew. Chem. Int. Ed.<\/em>, 2022<\/strong>, 61<\/em>, e202113947<\/p>\n\n\n\n

Highlighted as a Hot Paper<\/strong><\/em><\/p>\n\n\n\n

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16) Palladium-catalyzed homocoupling of highly fluorinated arylboronates: studies of the influence of strongly vs weakly coordinating solvents on the reductive elimination process<\/a><\/p>\n\n\n\n

Yudha P. Budiman, Arumugam Jayaraman, Alexandra Friedrich, Florian Kerner, Udo Radius and Todd B. Marder<\/p>\n\n\n\n

J. Am. Chem. Soc.<\/em>, 2020<\/strong>, 142<\/em>, 6036\u22126050<\/p>\n\n\n\n

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15) Hydrophosphination of boron\u2013boron multiple bonds<\/a><\/p>\n\n\n\n

Tom E. Stennett, Arumugam Jayaraman, Tobias Br\u00fcckner, Lena Schmeider and Holger Braunschweig<\/p>\n\n\n\n

Chem. Sci.<\/em>, 2020<\/strong>, 11<\/em>, 1335\u20131341<\/p>\n\n\n\n

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14) Revisiting the reduction of indoles by hydroboranes: A combined experimental and computational study<\/a><\/p>\n\n\n\n

Arumugam Jayaraman, Henry Powell-Davies and Fr\u00e9d\u00e9ric-G. Fontaine<\/p>\n\n\n\n

Tetrahedron<\/em>, 2019<\/strong>, 75<\/em>, 2118\u20132127<\/p>\n\n\n\n

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13) Alkyne insertion into P\u2013C(sp2<\/sup>) bonds as a route to fused phospholes: Transition-metal-like reactivity at phosphorus<\/a><\/p>\n\n\n\n

Shrikant Nilewar, Arumugam Jayaraman <\/strong>and Brian T. Sterenberg<\/p>\n\n\n\n

Organometallics<\/em>, 2018<\/strong>, 37<\/em>, 4699\u20134710<\/p>\n\n\n\n

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12) Practical and scalable synthesis of borylated heterocycles using bench stable precursor of metal-free Lewis pair catalysts<\/a><\/p>\n\n\n\n

Arumugam Jayaraman, Luis C. Misal Castro and Fr\u00e9d\u00e9ric-G. Fontaine<\/p>\n\n\n\n

Org. Process Res. Dev.<\/em>, 2018<\/strong>, 22<\/em>, 1489\u20131499<\/p>\n\n\n\n

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11) Metal-free borylative dearomatization of indoles: exploring the divergent reactivity of aminoborane C\u2013H borylation catalysts<\/a><\/p>\n\n\n\n

Arumugam Jayaraman, Luis C. Misal Castro, Vincent Desrosiers and Fr\u00e9d\u00e9ric-G. Fontaine<\/p>\n\n\n\n

Chem. Sci.<\/em>, 2018<\/strong>, 9<\/em>, 5057\u22125063<\/p>\n\n\n\n

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10) Sequential electrophilic substitution reactions of tungsten-coordinated phosphenium ions and phosphine triflates<\/a><\/p>\n\n\n\n

Arumugam Jayaraman, Shrikant Nilewar, Tyler V. Jacob and Brian T. Sterenberg<\/p>\n\n\n\n

ACS Omega<\/em>, 2017<\/strong>, 2<\/em>,7849\u22127861<\/p>\n\n\n\n

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9) Metal-free borylation of heteroarenes using ambiphilic aminoboranes: On the importance of sterics in frustrated Lewis pair C-H bond activation<\/a><\/p>\n\n\n\n

Julien L. Lavergne, Arumugam Jayaraman, Luis C. Misal Castro, \u00c9tienne Rochette and Fr\u00e9d\u00e9ric-G. Fontaine<\/p>\n\n\n\n

J. Am. Chem. Soc.<\/em>, 2017<\/strong>, 139<\/em>, 14714\u221214723<\/p>\n\n\n\n

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8) A potent synthetic inorganic antibiotic with activity against drug-resistant pathogens<\/a><\/p>\n\n\n\n

Shelby Hubick, Arumugam Jayaraman, Shelby Reid, Jane Alcorn, John Stavrinides and Brian T. Sterenberg<\/p>\n\n\n\n

Sci. Rep. (Nature)<\/em>, 2017<\/strong>, 7<\/em>, 41999 <\/p>\n\n\n\n

Highlighted in<\/em><\/p>\n\n\n\n

CBC<\/a><\/td>Leader Post<\/a><\/td>USask<\/a><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n
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7) Phosphorus\u2013carbon bond forming reactions of diphenylphosphenium and diphenylphosphine triflate complexes of tungsten<\/a><\/p>\n\n\n\n

Arumugam Jayaraman <\/strong>and Brian T. Sterenberg<\/p>\n\n\n\n

Organometallics<\/em>, 2016<\/strong>, 35<\/em>, 2367\u22122377<\/p>\n\n\n\n

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6) Sequential electrophilic P\u2013C bond formation in metal-coordinated chlorophosphines<\/a><\/p>\n\n\n\n

Arumugam Jayaraman, Tyler V. Jacob, Jeff Bisskey and Brian T. Sterenberg<\/p>\n\n\n\n

Dalton Transactions<\/em>, 2015<\/strong>, 44<\/em>, 8788\u22128791<\/p>\n\n\n\n

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5) Reactivity of a dichlorophosphido complex. Nucleophilic substitution reactions at metal-coordinated phosphorus<\/a><\/p>\n\n\n\n

Rakesh Rajagopalan, Arumugam Jayaraman <\/strong>and Brian T. Sterenberg<\/p>\n\n\n\n

J. Organomet. Chem.<\/em>, 2014<\/strong>, 761<\/em>, 84\u221292<\/p>\n\n\n\n

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4) Electrophilic aromatic substitution reactions of a tungsten-coordinated phosphirenyl triflate<\/a><\/p>\n\n\n\n

Arumugam Jayaraman <\/strong>and Brian T. Sterenberg<\/p>\n\n\n\n

Organometallics<\/em>, 2014<\/strong>, 33<\/em>, 522\u2212530<\/p>\n\n\n\n

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3) Facile phosphorus\u2013carbon bond formation using a tungsten-coordinated phosphirenyl cation<\/a><\/p>\n\n\n\n

Arumugam Jayaraman <\/strong>and Brian T. Sterenberg<\/p>\n\n\n\n

Organometallics<\/em>, 2013<\/strong>, 32<\/em>, 745\u2212747<\/p>\n\n\n\n

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2) The mechanism of permanganate oxidation of sulfides and sulfoxides<\/a><\/p>\n\n\n\n

Arumugam Jayaraman <\/strong>and Allan L. L. East<\/p>\n\n\n\n

J. Org. Chem.<\/em>, 2012<\/strong>, 77<\/em>, 351\u2212356<\/p>\n\n\n\n

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1) Tungsten (II)-catalyzed rearrangements of norbornadiene: Effects of alternative complexation stages<\/a><\/p>\n\n\n\n

Arumugam Jayaraman, Greg M. Berner, Lynn M. Mihichuk, and Allan L. L. East<\/p>\n\n\n\n

J. Mol. Catal. A: Chem.<\/em>, 2011<\/strong>, 351<\/em>, 143\u2212153<\/p>\n\n\n\n

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Patents filed<\/p>\n\n\n\n

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1) A potent synthetic inorganic antibacterial with activity against drug-resistant pathogens
Arumugam Jayaraman, Brian T. Sterenberg and John Stavrinides
Filed as: U. S. Patent (Application No. CA 2017-2972079, application date 29.06.2017)<\/p>\n<\/div>\n","protected":false},"excerpt":{"rendered":"

PUBLICATIONS GoogleScholar ORCiD ResearchGate 30) Olefin \u03c0-coordination chemistry at low-oxidation-state boron Maximilian Michel, Marco Weber, Arumugam Jayaraman, Rian D. Dewhurst, Ivo Krummenacher, Christian Voigt, Marcel H\u00e4rterich, Alfredo Vargas, and Holger Braunschweig\u2009\u2009 Nature Chem., 2026, 18, 135\u2212141 Highlighted in: Uni-Wuerzburg EurekAlert Mirage News Chem Europe ScienMag My Science Ingenieur.de LaRep\u00fablica.es Bioengineer.org phys.org Jura Forum Analytik NEWS […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-152","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/jayaramangroup.faculty.unlv.edu\/index.php?rest_route=\/wp\/v2\/pages\/152","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/jayaramangroup.faculty.unlv.edu\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/jayaramangroup.faculty.unlv.edu\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/jayaramangroup.faculty.unlv.edu\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/jayaramangroup.faculty.unlv.edu\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=152"}],"version-history":[{"count":179,"href":"https:\/\/jayaramangroup.faculty.unlv.edu\/index.php?rest_route=\/wp\/v2\/pages\/152\/revisions"}],"predecessor-version":[{"id":1524,"href":"https:\/\/jayaramangroup.faculty.unlv.edu\/index.php?rest_route=\/wp\/v2\/pages\/152\/revisions\/1524"}],"wp:attachment":[{"href":"https:\/\/jayaramangroup.faculty.unlv.edu\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=152"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}